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Question Details
 
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Question No.:  5261 Category :  Refining Operations
Date Posted:  7/28/2010
Subject: Amine column operation
 
Question:
Has anyone faced the problem of high H2S in the fuel gas outlet from amine tower? It is observed that the H2S absorption was affected by CO2 absorption. Simulation of the column is done. It was observed that actual CO2 in the fuel gas outlet is less that the simulation output. This represents the absorption kinetics towards CO2 than H2S. Is there any trick to control the absorption kinetics towards H2S/CO2?
Submitted by :
Name:
Company Name:
Location:
EMail:

Nikhil Darak

Jamnagar, Gujarat, India 
nikhildarak@rediffmail.com


 

Number of responses : 3
Response 5261-1
Date : 7/31/2010

Each amine has a different selectivity between absorbing H2S and CO2. You may not have the appropriate amine for your situation. The most common amine for this service in refineries was DEA, and now is MDEA.

Name - Ralph Ragsdale
CompanyName - Ragsdale Refining Courses
Location - Houston, TX, USA
Email - ragsdales@juno.com

Response 5261-2
Date : 8/4/2010

Please look at the amine type. MEA is strongly selective for the absorption of CO2 followed by DEA. Consider the amine to MDEA.

Name - Samuel Sinanan
CompanyName - IPSL
Location - Point Lisas, Trinidad
Email - samuel.sinanan@gmail.com

Response 5261-3
Date : 9/2/2010

I think you can improve the selectivity by reducing the temperature in the tower. Is this an option?

Name - Daniele Colle
CompanyName - BP Rotterdam
Location - Europoort Rt , The Netherlands
Email - daniele.colle@bp.com

 




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